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Why? Because accounting, and even more so chemistry, is a highly quantitative exercise. Mass is always conserved in a chemical reaction, and accurate masses, which are the weighted averages of the isotopic masses, are necessary to demonstrate this conservation of mass. For the lighter , hydrogen, carbon, and oxygen, this is not so important in that there is normally only the ONE isotope. But for the heavier elements, especially where the isotopic distribution is large, and we get fractional atomic masses, we must account for the isotopic distribution.

PS If my account were debited $£7-50$ instead of the $£7-49$ purchase price, I would raise merry hell, and demand satisfaction from my bank manager.

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