So, you know that your atom contains
$16$ protons$18$ neutrons$16$ electrons
Right from the start, you know that you're indeed dealing with a neutral atom, since the number of protons it has in its nucleus is equal to the number of electrons it has surrounding its nucleus.
Now, an atom's ,
In your case, you are told that the atom contains
$Z = 16$
A quick look in will reveal that you're dealing with an atom of sulfur,
An atom's ,
$A = Z + "no. of neutrons"$
In your case, the atom contains
$A = 16 + 18 = 34$
Finally, focus on the atom's , which you know that must account for a total of
$"S: " 1s^2 2s^2 2p^6 3s^2 3p^4$
Its , which uses the of neon,
$"S: " ["Ne"] 3s^2 3p^4$