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$21.3s = 0.693/k$
$therefore k approx 3.25*10^-2s^-1$

$ln(1/8) = -3.25*10^-2s^-1 * t$
$therefore t approx 64.0s$

Each equation I used is assuming this reaction's kinetics are of the first order, which is cited. The first equation is a simplified version for the half life of a first order reactant, and the second equation is the general equation for first order reactions in chemical kinetics.

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