When you look at the big picture, what you have is heat flowing out of solid iron and cooling it down.
So, you have to use the heat flow equation:
$\mathbf(q = msDeltaT)$ where:
$q$ is the heat flow in$"J"$ .$m$ is the mass of the object in$"g"$ .$s$ is the capacity of the object in$"J/g"cdot""^@ "C"$ .$DeltaT$ is the change in temperature of the iron in$""^@ "C"$ .
First, convert the heat from
$-75$ $cancel"cal" xx "4.184 J"/cancel"cal" = -"313.8 J"$
Now what you have is:
$color(blue)(m_"Fe") = q_"Fe"/(s_"Fe"DeltaT_"Fe")$
$= q_"Fe"/(s_"Fe"[T_f^"Fe" - T_i^"Fe"])$
$= (-313.8 cancel("J"))/((0.444 cancel("J")"/g"cdotcancel(""^@ "C"))[(-25.2cancel(""^@ "C")) - (21.4cancel(""^@ "C"))])$
$=$ $color(blue)("15.2 g Fe")$