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Calcium bromide speciates in aqueous solution according to the following equation.........

$CaBr_2(s) stackrel(H_2O)rarrCa^(2+) + 2Br^-$

And thus for every metal ion there are necessarily two bromide ions.

Here by specification,

$[Br^-]=0.10*mol*L^-1$, and thus $[Ca^(2+)]=1/2xx[Br^-]=1/2xx0.10*mol*L^-1=0.050*mol*L^-1$

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