So we have the $"%calcium carbonate, "m/m$. We are not finished yet, because we have to address the percentage by mass of calcium metal in calcium carbonate:
$%Ca=(40.08*g*mol^-1)/(100.09*g*mol^-1)=40%$ with respect to calcium carbonate.
And thus the $%Ca$ IN THE SAMPLE
$=(1.33*g)/(2.03*g)xx(40.08*g*mol^-1)/(100.09*g*mol^-1)xx100%=26.2%$
We have assumed that ALL of the calcium metal is present as the carbonate.