First, convert percentages into grams.
$ 32.39 % = 32.39 g$
$22.53% = 22.53 g$
$45.07% = 45.07 g$
Second, convert the grams into moles.
$"32.39 g"/("22.99 g/mol Na")= "1.409 mol Na"$
$"22.53 g"/"32.06 g/mol S" = "0.7027 mol S"$
$"45.07 g"/"16.00 g/mol O" = "2.817 mol O"$
Third, convert the moles into a ratio of atoms.
$"2.817 mol O"/"0.7027 mol S" = "4.009 O"/"1 S"$
$"1.409 mol Na"/"0.7027 mol S" = "2.005 Na"/"1 S"$
Rounding to integers, the ratio is 1 S: 2 Na : 4 O
$Na_2 S O_4$