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The of tin in the compound will be equal to the ratio between the mass of tin and the mass of the compound, multiplied by $100$.

$color(blue)("% Sn" = m_(Sn)/m_"total" xx 100)$

Your initial sample of tine reacts completely with $"24.49 g"$ of chlorine, which means that the total mass of the compound will be

$m_"total" = "20.50 g" + "24.49 g" = "44.99 g"$

The of tin in the compound will be

$(20.50 color(red)(cancel(color(black)("g"))))/(44.99color(red)(cancel(color(black)("g")))) xx 100 = color(green)("45.57% Sn")$

Now, to get the compound's , use the molar masses of the two to determine how many moles of each you have in that sample

$20.50 color(red)(cancel(color(black)("g"))) * "1 mole Sn"/(118.71color(red)(cancel(color(black)("g")))) = "0.17269 moles Sn"$

$24.49 color(red)(cancel(color(black)("g"))) * "1 mole Cl"/(35.453 color(red)(cancel(color(black)("g")))) = "0.69077 moles Cl"$

Divide both values by the smallest one to get the that exists between the two elements in the compound

$"For Sn: " (0.17269 color(red)(cancel(color(black)("moles"))))/(0.17269 color(red)(cancel(color(black)("moles")))) = 1$

$"For Cl: " (0.69077 color(red)(cancel(color(black)("moles"))))/(0.17269color(red)(cancel(color(black)("moles")))) ~~ 4$

The empirical formula of the compound, which tells you the smallest whole number ratio that exists between the two elements, will be

$"Sn"_1"Cl"_4 implies color(green)("SnCl"_4)$

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