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Putting 3 as cooefficient for sulfur trioxide will balance the chemical equation. Check the number of atoms of each element by having an inventory.

Reactant Side:
$Al=2xx1=2$
$S=3xx1xx1=3$
$O=3xx4xx1=12$

Product Side:
$Al=2xx1=2$
$S=1xx3=3$
$O=3xx1 + 3xx3 = 12$

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