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The idea here is that you need to use the chemical formula for magnesium nitride, $"Mg"_3"N"_2$, to calculate the mass of one mole of the compound, i.e. its molar mass.

So, magnesium nitride is an ionic compound made up of magnesium cations, $"Mg"^(2+)$, and nitride anions, $"N"^(3-)$. The subscripts used in the compound's chemical formula tell you how many ions you get in one formula unit of magnesium nitride.

In this case, you have

$"Mg"_ color(red)(3) "N"_ color(blue)(2) -> color(red)(3)"Mg"^color(blue)(2+) + color(blue)(2)"N"^color(red)(3-)$

So, one formula unit of magnesium nitride contains $color(red)(3)$ magnesium cations and $color(blue)(2)$ nitride anions.

This means that one mole of magnesium nitride will contain $color(red)(3)$ moles of magnesium cations and $color(blue)(2)$ moles of nitride anions.

Now, you know that one mole of magnesium has a mass of $"24.31 g"$. Since you get three moles of magnesium cations per mole of the compound, magnesium's contribution to the molar mass will be

$color(red)(3) color(red)(cancel(color(black)("moles Mg"^(2+)))) * "24.31 g"/(1color(red)(cancel(color(black)("mole Mg"^(2+))))) = "72.93 g"$

Likewise, you know that one mole of nitrogen has a mass of $"14.01 g"$. Since you get two moles of nitride anions per mole of the compound, nitrogen's contribution will be

$color(blue)(2) color(red)(cancel(color(black)("moles N"^(3-)))) * "14.01 g"/(1color(red)(cancel(color(black)("mole N"^(3-))))) = "28.02 g"$

Therefore, the total mass of one mole of magnesium nitride will be

$"72.93 g" + "28.02 g" = "100.95 g"$

Since this is how many grams you get per mole, you can say that the molar mass will be

$"molar mass" = color(green)(|bar(ul(color(white)(a/a)color(black)("100.95 g mol"^(-1))color(white)(a/a)|)))$

I'll leave the answer rounded to five , despite the fact that you only have four sig figs for the molar masses of the two .

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