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The idea here is that the of the gas tells you the mass of this gas that occupies exactly $"1 L"$ at some unspecified conditions for pressure and temperature.

In this case, you know that the gas had a density of $"2.50 g L"^(-1)$. This tells you that $"2.50 g"$ of this gas occupy exactly $"1 L"$ at the conditions for pressure and temperature used in the experiment.

You also know that the total volume of the flask is equal to $"5.00 L"$. At this point, you can use the density of the gas to calculate the mass of gas needed in order for the sample to occupy the given volume.

$5.00 color(red)(cancel(color(black)("L"))) * "2.50 g"/(1color(red)(cancel(color(black)("L")))) = "12.5 g"$

Now, in order to find the molar mass of the gas, you need to find the mass of exactly $1$ mole. You know that this sample contains $0.211$ moles of gas and has a mass of $"12.5 g"$, so you can say that $1$ mole will have a mass of

$1 color(red)(cancel(color(black)("mole gas"))) * "12.5 g"/(0.211 color(red)(cancel(color(black)("moles gas")))) = "59.24 g"$

Therefore, you can say that the molar mass of the gas is equal to

$color(darkgreen)(ul(color(black)("molar mass = 59.2 g mol"^(-1)))$

This means that $1$ mole of this gas has a mass of $"59.2 g"$.

The answer is rounded to three .

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