Which compound in each pair is more water soluble? Which compound in each pair is more soluble in an organic solvent? (a) CH3CH2CH2CH3 or CH3CH2CH2CH2CO2H (b) CH3(CH2)4COOH or CH3(CH2)4COO–Na+.

Md Ariful Islam

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(a) CH3CH2CH2CH3 is more soluble in non-polar organic solvents because it is also non-polar. CH3CH2CH2CH2CO2H is more soluble in water than CH3CH2CH2CH3.

(b) CH3(CH2)4COOH is more soluble in organic solvents. CH3(CH2)4COO–Na+ is more soluble in water because of its ionic nature.

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