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If you have a substance with nonpolar molecules , the only that exist are London-Dispersion forces, which are very weak.

However, if you have a substance with polar molecules, then not only are there London-Dispersion forces, but also Dipole-Dipole forces, which are stronger than London-Dispersion forces.

Therefore, a polar substance will have a stronger attraction between its molecules than a substance with nonpolar molecules.

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