Thionyl chloride reacts quantitatively (and violently) with water as represented by the following reaction:
$SOCl_2(l) + 2H_2O(l) rarr SO_2(g)uarr + 2HCl(aq)+Delta$
$"Moles of thionyl chloride"=(35.0*g)/(118.97*g*mol^-1)=0.294*mol.$
And CLEARLY, thionyl chloride is the reagent in deficiency; $500.0*g$ of water is a HUGE molar quantity.