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Sodium peroxide can be thermolyzed to give dioxygen gas...

$Na_2O_2(s) +Delta rarr Na_2O(s) + 1/2O_2(g)uarr$

But with water, we simply get an acid base reaction....

$Na_2O_2(s) +2H_2O(l) rarr 2NaOH(aq) + H_2O_2(aq)$...

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