There is no coefficient in front of the $N_2$ in the reactants. This means that there is one mole of $N_2$ required in the balanced equation.
There is a 2 coefficient in front of the $NH_3$ in the products.
This is a 1:2 or 2:1 ratio. Since the desired outcome is $NH_3$ put the 2 on top and the 1 on the bottom
$ 6 (N_2) xx 2/1 = NH_3$
$ 6 xx 2 = 12 (NH_3)$