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So $4.50$ mol $AlCl_3harr3xx4.50=13.50$ mol $Cl^-$

1 mol contains $~~6.02xx10^23$ particles, so the answer is:

$n_(Cl^-)=13.50xx6.02xx10^23=81.27xx10^23~~8.13xx10^24$

(rounded to 3 significant digit because of the $4.50$)